Safety Data Sheet - Acid Free Primer
Claw Culture Cosmetics Limited
Contact Information: Claw Culture Cosmetics Limited, c/o Unit 6 Park Road Industrial Estate, BACUP, Lancashire OL13 0BW – sales@clawculture.com
Website: www.clawculture.com
Emergency Contact Number: 07495 930061
Product Name: Acid Free Nail Primer
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
EC regulation criteria 1272/2008 (CLP)
Danger, Flam. Liq. 2, Highly flammable liquid and vapour.
Warning, Eye Irrit. 2, Causes serious eye irritation.
Warning, Skin Sens. 1, May cause an allergic skin reaction.
Warning, STOT SE 3, May cause drowsiness or dizziness.
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2. Label elements
Hazard pictograms:
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Danger
Hazard statements:
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H336 May cause drowsiness or dizziness.
Precautionary statements:
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing
protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water [or shower].
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P405 Store locked up.
P501 Dispose of contents/container in accordance with applicable regulations.
Special Provisions:
None
Contains
ethyl acetate
acetone; propan-2-one; propanone
Glycerol, propoxylated, esters with acrylic acid
Special provisions according to Annex XVII of REACH and subsequent amendments:
None
2.3. Other hazards
No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%
Other Hazards:
No other hazards
SECTION 3: Composition/information on ingredients
3.1. Substances
N.A.
3.2. Mixtures
Hazardous components within the meaning of the CLP regulation and related classification or
which have been assigned Occupational Exposure Limits:
Qty Name Ident. Number Classification
< 90% ethyl acetate Index
number:
607-022-00-5
CAS: 141-78-6
EC: 205-500-4
2.6/2 Flam. Liq. 2 H225
3.3/2 Eye Irrit. 2 H319
3.8/3 STOT SE 3 H336
EUH066
< 7% acetone; Index 606-001-00-8 2.6/2 Flam. Liq. 2 H225
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propan-2-one;
propanone
number:
CAS: 67-64-1
EC: 200-662-2
REACH No.: 01-21194713
30-49
3.3/2 Eye Irrit. 2 H319
3.8/3 STOT SE 3 H336
EUH066
< 2.5% Glycerol, propoxylated,
esters with acrylic acid
CAS: 52408-84-1
EC: 500-114-5
REACH No.: 01-21194879
48-12
3.4.2/1 Skin Sens. 1 H317
3.3/2 Eye Irrit. 2 H319
SECTION 4: First aid measures
4.1. Description of first aid measures
In case of skin contact:
Remove contaminated clothing immediately and dispose of safely.
After contact with skin, wash immediately with soap and water.
In case of eye contact:
After contact with the eyes, rinse with water with the eyelids open for 15 minutes, then seek
prompt medical advice.
Protect uninjured eye.
In case of ingestion:
Do not induce vomiting. Immediately rinse mouth and drink plenty of water. Keep person
under observation. If person becomes uncomfortable remove to hospital and bring these
instructions.
In case of inhalation:
Remove casualty to fresh air and keep warm and at rest. For breathing difficulties oxygen
may be necessary.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
In case of accident or experiencing symptoms, seek medical advice immediately (show
directions for use or safety data sheet if possible).
Treatment:
None
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
CO2 or Dry chemical fire extinguisher.
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
Move undamaged containers from immediate hazard area if it can be done safely.
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SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non emergency personnel:
Wear personal protection equipment.
Remove all sources of ignition.
Remove persons to safety.
See protective measures under point 7 and 8.
For emergency responders:
Wear personal protection equipment.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose of it.
In case of escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: sand, earth, vermiculite etc.
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Ensure empty containers have been cleaned of any residue before reuse.
Before transferring product, ensure that there are no traces of incompatible material residues
in the containers.
See also section 8 for recommended protective equipment.
Advice on general occupational hygiene:
Contaminated clothing should be changed before entering eating areas.
Do not eat or drink while working.
7.2. Conditions for safe storage, including any incompatibilities
Always keep in a well ventilated place.
Store at below 20 °C. Keep away from unguarded flame and heat sources. Avoid direct
exposure to sunlight.
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to
sunlight.
Avoid accumulating electrostatic charge.
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Cool and adequately ventilated.
Safety electric system.
7.3. Specific end use(s)
See section 1.2
None in particular
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
ethyl acetate
- OEL Type: EH40/2005 - TWA(8h): 200 ppm - STEL(15min): 400 ppm
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- OEL Type: EU - TWA(8h): 734 mg/m3, 200 ppm - STEL: 1468 mg/m3, 400 ppm
- OEL Type: ACGIH - TWA(8h): 400 ppm - Notes: URT and eye irr
acetone; propan-2-one; propanone
- OEL Type: EU - TWA(8h): 1210 mg/m3, 500 ppm
- OEL Type: ACGIH - TWA(8h): 250 ppm - STEL: 500 ppm - Notes: A4, BEI - URT
and eye irr, CNS impair
DNEL Exposure Limit Values
ethyl acetate
Worker Industry: 734 mg/m3 - Consumer: 367 mg/m3 - Exposure: Human Inhalation -
Frequency: Long Term, systemic effects
Worker Industry: 63 mg/kg - Consumer: 37 mg/kg - Exposure: Human Dermal -
Frequency: Long Term, systemic effects - Endpoint: bw/day
Consumer: 4.5 mg/kg - Exposure: Human Oral - Frequency: Long Term, systemic
effects - Endpoint: bw/day
acetone; propan-2-one; propanone
Worker Industry: 186 mg/kg - Consumer: 62 mg/kg - Exposure: Human Dermal -
Frequency: Long Term, systemic effects - Endpoint: bw/day
Worker Industry: 2420 mg/m3 - Exposure: Human Inhalation - Frequency: Short Term,
local effects
Worker Industry: 1210 mg/m3 - Consumer: 200 mg/m3 - Exposure: Human Inhalation -
Frequency: Long Term, systemic effects
Consumer: 62 mg/kg - Exposure: Human Oral - Frequency: Long Term, systemic
effects - Endpoint: bw/day
PNEC Exposure Limit Values
ethyl acetate
Target: Fresh Water - Value: 0.24 mg/l
Target: Marine water - Value: 0.024 mg/l
Target: Intermittent releases - Value: 1.65 mg/l
Target: Freshwater sediments - Value: 1.15 mg/kg
Target: Soil (agricultural) - Value: 0.148 mg/kg
acetone; propan-2-one; propanone
Target: Fresh Water - Value: 10.6 mg/l
Target: Marine water - Value: 1.06 mg/l
Target: Freshwater sediments - Value: 3.04 mg/kg
Target: Soil (agricultural) - Value: 33.3 mg/l
8.2. Exposure controls
Eye protection:
Use close fitting safety goggles.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or
viton.
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or
rubber.
Respiratory protection:
Use adequate protective respiratory equipment.
Thermal Hazards:
None
Environmental exposure controls:
None
Appropriate engineering controls:
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None
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Properties Value Method: Notes
Physical state: Liquid -- --
Colour: N.A. -- --
Odour: N.A. -- --
Melting point/freezing
point:
N.A. -- --
Boiling point or initial
boiling point and boiling
range:
N.A. -- --
Flammability: Flam. Liq. 2,
H225
-- --
Lower and upper explosion
limit:
N.A. -- --
Flash point: 21°C -- --
Auto-ignition temperature: N.A. -- --
Decomposition
temperature:
N.A. -- --
pH: 6 -- --
Kinematic viscosity: N.A. -- --
Solubility in water: N.A. -- --
Solubility in oil: N.A. -- --
Partition coefficient
n-octanol/water (log value):
N.A. -- --
Vapour pressure: N.A. -- --
Density and/or relative
density:
N.A. -- --
Relative vapour density: N.A. -- --
Particle characteristics:
Particle size: N.A. -- --
9.2. Other information
No other relevant information
SECTION 10: Stability and reactivity
10.1. Reactivity
It may generate dangerous reactions (See subsections below)
10.2. Chemical stability
It may generate dangerous reactions (See subsections below)
10.3. Possibility of hazardous reactions
None
10.4. Conditions to avoid
Avoid accumulating electrostatic charge.
10.5. Incompatible materials
Avoid contact with combustible materials. The product could catch fire.
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10.6. Hazardous decomposition products
None.
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Toxicological information of the product:
Acid Free Nail Primer
- a) acute toxicity
Not classified
Based on available data, the classification criteria are not met
- b) skin corrosion/irritation
Not classified
Based on available data, the classification criteria are not met
- c) serious eye damage/irritation
The product is classified: Eye Irrit. 2 H319
- d) respiratory or skin sensitisation
The product is classified: Skin Sens. 1 H317
- e) germ cell mutagenicity
Not classified
Based on available data, the classification criteria are not met
- f) carcinogenicity
Not classified
Based on available data, the classification criteria are not met
- g) reproductive toxicity
Not classified
Based on available data, the classification criteria are not met
- h) STOT-single exposure
The product is classified: STOT SE 3 H336
- i) STOT-repeated exposure
Not classified
Based on available data, the classification criteria are not met
- j) aspiration hazard
Not classified
Based on available data, the classification criteria are not met
Toxicological information of the main substances found in the product:
ethyl acetate
- a) acute toxicity:
Test: LD50 - Route: Oral - Species: Rabbit 4934 mg/kg
Test: LD50 - Route: Skin - Species: Rabbit > 20000 mg/kg
Test: LC50 - Route: Inhalation - Species: Rat > 22.5 mg/l
acetone; propan-2-one; propanone
- a) acute toxicity:
Test: LD50 - Route: Oral - Species: Rat = 5800 mg/kg
Test: LD50 - Route: Skin - Species: Rat = 15800 mg/kg
Test: LC50 - Route: Inhalation - Species: Rat = 76 mg/l
Glycerol, propoxylated, esters with acrylic acid
- a) acute toxicity:
Test: LD50 - Route: Oral - Species: Rat > 2000 mg/kg bw
Test: LD50 - Route: Skin - Species: Rabbit > 2000 mg/kg bw
11.2. Information on other hazards
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Endocrine disrupting properties:
No endocrine disruptor substances present in concentration >= 0.1%
SECTION 12: Ecological information
12.1. Toxicity
Adopt good working practices to avoid releasing the product into the environment.
Acid Free Nail Primer
Not classified for environmental hazards
Based on available data, the classification criteria are not met
ethyl acetate
- a) Aquatic acute toxicity:
Endpoint: LC50 - Species: Fish 230 mg/l - Duration h: 96
Endpoint: EC50 - Species: Daphnia 165 mg/l - Duration h: 48
Endpoint: LC50 - Species: Algae 5600 mg/l - Duration h: 48
acetone; propan-2-one; propanone
- a) Aquatic acute toxicity
Endpoint: LC50 - Species: Oncorhynchus mykiss (rainbow trout) = 5540 mg/l - Duration
h: 96
Endpoint: EC50 - Species: Daphnia = 8840 mg/l - Duration h: 48
Glycerol, propoxylated, esters with acrylic acid
- a) Aquatic acute toxicity:
Endpoint: LC50 - Species: Danio rerio (zebra fish) 5.74 mg/l - Duration h: 96
Endpoint: EC50 - Species: Daphnia 91.4 mg/l - Duration h: 48
Endpoint: EC50 - Species: Desmodesmus subspicatus (green algae) 12.2 mg/l -
Duration h: 72
Endpoint: NOEC - Species: Desmodesmus subspicatus (green algae) 2.06 mg/l -
Duration h: 72
12.2. Persistence and degradability
ethyl acetate
Biodegradability: Readily biodegradable - %: 69
acetone; propan-2-one; propanone
Biodegradability: Readily biodegradable
Glycerol, propoxylated, esters with acrylic acid
Biodegradability: Readily biodegradable
12.3. Bioaccumulative potential
ethyl acetate
Not bioaccumulative - Test: Kow - Partition coefficient -3
acetone; propan-2-one; propanone
Not bioaccumulative
Glycerol, propoxylated, esters with acrylic acid
Low potential for bioaccumulation.
12.4. Mobility in soil
Glycerol, propoxylated, esters with acrylic acid
Test: Koc 100
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Endocrine disrupting properties
No endocrine disruptor substances present in concentration >= 0.1%
12.7. Other adverse effects
None
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SECTION 13: Disposal considerations
13.1. Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled
conditions. In so doing, comply with the local and national regulations currently in force.
SECTION 14: Transport information
14.1. UN number or ID number
ADR-UN Number: 1993
IATA-UN Number: 1993
IMDG-UN Number: 1993
14.2. UN proper shipping name
ADR-Shipping Name: FLAMMABLE LIQUID, N.O.S. (ethyl acetate, acetone;
propan-2-one; propanone)
IATA-Shipping Name: FLAMMABLE LIQUID, N.O.S. (ethyl acetate, acetone;
propan-2-one; propanone)
IMDG-Shipping Name: FLAMMABLE LIQUID, N.O.S. (ethyl acetate, acetone;
propan-2-one; propanone)
14.3. Transport hazard class(es)
ADR-Class: 3
ADR - Hazard identification number: 33
IATA-Class: 3
IATA-Label: 3
IMDG-Class: 3
14.4. Packing group
ADR-Packing Group: II
IATA-Packing group: II
IMDG-Packing group: II
14.5. Environmental hazards
ADR-Enviromental Pollutant: No
IMDG-Marine pollutant: No
IMDG-EmS: F-E , S-E
14.6. Special precautions for user
ADR-Subsidiary hazards: -
ADR-S.P.: 274 601 640C
ADR-Transport category (Tunnel restriction code): 2 (D/E)
IATA-Passenger Aircraft: 353
IATA-Subsidiary hazards: -
IATA-Cargo Aircraft: 364
IATA-S.P.: A3
IATA-ERG: 3H
IMDG-Subsidiary hazards: -
IMDG-Stowage and handling: Category B
IMDG-Segregation: -
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14.7. Maritime transport in bulk according to IMO instruments
N.A.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) n. 2020/878
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Regulation (EU) n. 2015/1221 (ATP 7 CLP)
Regulation (EU) n. 2016/918 (ATP 8 CLP)
Regulation (EU) n. 2016/1179 (ATP 9 CLP)
Regulation (EU) n. 2017/776 (ATP 10 CLP)
Regulation (EU) n. 2018/669 (ATP 11 CLP)
Regulation (EU) n. 2018/1480 (ATP 13 CLP)
Regulation (EU) n. 2019/521 (ATP 12 CLP)
Regulation (EU) n. 2020/217 (ATP 14 CLP)
Regulation (EU) n. 2020/1182 (ATP 15 CLP)
Regulation (EU) n. 2021/643 (ATP 16 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation
(EC) 1907/2006 (REACH) and subsequent modifications:
Restrictions related to the product:
Restriction 3
Restriction 40
Restrictions related to the substances contained:
Restriction 75
Where applicable, refer to the following regulatory provisions :
Directive 2012/18/EU (Seveso III)
Regulation (EC) nr 648/2004 (detergents).
Dir. 2004/42/EC (VOC directive)
Provisions related to directive EU 2012/18 (Seveso III):
Seveso III category according to Annex 1, part 1
Product belongs to category: P5c
15.2. Chemical safety assessment
A Chemical Safety Assessment has not been carried out for the mixture.
SECTION 16: Other information
Full text of phrases referred to in Section 3:
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
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EUH066 Repeated exposure may cause skin dryness or cracking.
H317 May cause an allergic skin reaction.
Hazard class and
hazard category
Code Description
Flam. Liq. 2 2.6/2 Flammable liquid, Category 2
Eye Irrit. 2 3.3/2 Eye irritation, Category 2
Skin Sens. 1 3.4.2/1 Skin Sensitisation, Category 1
STOT SE 3 3.8/3 Specific target organ toxicity - single exposure,
Category 3
Classification and procedure used to derive the classification for mixtures according to Regulation
(EC) 1272/2008 [CLP]:
Classification according to Regulation (EC) Nr.
1272/2008
Classification procedure
Flam. Liq. 2, H225 On basis of test data
Eye Irrit. 2, H319 Calculation method
Skin Sens. 1, H317 Calculation method
STOT SE 3, H336 Calculation method
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
Nostrand Reinold
The information contained herein is based on our state of knowledge at the above-specified date. It
refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to
the specific use intended.
This MSDS cancels and replaces any preceding release.
ADR: European Agreement concerning the International Carriage of
Dangerous Goods by Road.
ATE: Acute Toxicity Estimate
ATEmix: Acute toxicity Estimate (Mixtures)
CAS: Chemical Abstracts Service (division of the American Chemical
Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of
Chemicals.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport
Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"
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(ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
PNEC: Predicted No Effect Concentration.
RID: Regulation Concerning the International Transport of Dangerous Goods
by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWA: Time-weighted average
WGK: German Water Hazard Class
Disclaimer
Claw Culture Cosmetics Limited works tirelessly to work with established manufacturers. It is the purchasers responsibility to ensure that the product is suitable for their requirements and undertake a personal Risk Assessment prior to use. All information appearing herein is obtained from the manufacturers. While the information is believed to be accurate to the best of our knowledge and belief Claw Culture Cosmetics Limited makes no representation as to its accuracy or sufficiency. Judgement as to the suitability of products are the purchasers sole responsibility