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        Claw Culture Cosmetics Limited

        Contact Information: Claw Culture Cosmetics Limited, c/o Unit 6 Park Road Industrial Estate, BACUP, Lancashire, OL13 0BW.  sales@clawculture.com

        Website: www.clawculture.com

        Emergency Contact Number: 07495 930061

        Product Name: Methacrylic Acid Primer

        SECTION 2: Hazards identification

        2.1. Classification of the substance or mixture

        EC regulation criteria 1272/2008 (CLP)

        Danger, Skin Corr. 1A, Causes severe skin burns and eye damage.

        Danger, Eye Dam. 1, Causes serious eye damage.

        Warning, STOT SE 3, May cause respiratory irritation.

        Warning, STOT SE 3, May cause drowsiness or dizziness.

        Adverse physicochemical, human health and environmental effects:

        No other hazards

        2.2. Label elements

        Hazard pictograms:

         

        Safety Data Sheet

        Methacrylic Acid Primer

         

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        Danger

        Hazard statements:

        H314 Causes severe skin burns and eye damage.

        H318 Causes serious eye damage.

        H335 May cause respiratory irritation.

        H336 May cause drowsiness or dizziness.

        Precautionary statements:

        P101 If medical advice is needed, have product container or label at hand.

        P102 Keep out of reach of children.

        P103 Read carefully and follow all instructions.

        P260 Do not breathe dust/fume/gas/mist/vapours/spray.

        P271 Use only outdoors or in a well-ventilated area.

        P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing

        protection.

        P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

        P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.

        Rinse skin with water [or shower].

        P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

        P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

        contact lenses, if present and easy to do. Continue rinsing.

        P312 Call a POISON CENTER/doctor if you feel unwell.

        P403+P233 Store in a well-ventilated place. Keep container tightly closed.

        P405 Store locked up.

        P501 Dispose of contents/container in accordance with applicable regulations.

        Special Provisions:

        PACK1 The packing must feature a safety lock for children.

        PACK2 The packing must have tactile indications of danger for blind people.

        Contains

        methacrylic acid; 2-methylpropenoic acid

        ethyl acetate

        butanone; ethyl methyl ketone

        Special provisions according to Annex XVII of REACH and subsequent amendments:

        None

        2.3. Other hazards

        No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%

        Other Hazards:

        No other hazards

         

        SECTION 3: Composition/information on ingredients

        3.1. Substances

        N.A.

        3.2. Mixtures

        Hazardous components within the meaning of the CLP regulation and related classification or

        which have been assigned.

        Occupational Exposure Limits:

        Qty Name Ident. Number Classification

        < 55% methacrylic acid;

        2-methylpropenoic acid

        Index

        number:

         

        607-088-00-5

        CAS: 79-41-4

        EC: 201-204-4

         

        3.2/1A Skin Corr. 1A H314

        3.1/4/Oral Acute Tox. 4 H302

         

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        3.1/4/Dermal Acute Tox. 4

        H312

        Specific Concentration Limits:

        C >= 1%: STOT SE 3 H335

         

        < 40% ethyl acetate Index

        number:

         

        607-022-00-5

        CAS: 141-78-6

        EC: 205-500-4

         

        2.6/2 Flam. Liq. 2 H225

        3.3/2 Eye Irrit. 2 H319

        3.8/3 STOT SE 3 H336

        EUH066

         

        < 20% butanone; ethyl methyl

        ketone

         

        Index

        number:

         

        606-002-00-3

        CAS: 78-93-3

        EC: 201-159-0

         

        2.6/2 Flam. Liq. 2 H225

        3.3/2 Eye Irrit. 2 H319

        3.8/3 STOT SE 3 H336

        EUH066

         

        SECTION 4: First aid measures

        4.1. Description of first aid measures

        In case of skin contact:

        OBTAIN IMMEDIATE MEDICAL ATTENTION.

        Remove contaminated clothing immediately and dispose of safely.

        After contact with skin, wash immediately with soap and water.

        In case of eye contact:

        After contact with the eyes, rinse with water with the eyelids open for 15 minutes, then seek prompt medical advice.

        Protect uninjured eye.

        In case of ingestion:

        Do NOT induce vomiting.

        In case of inhalation:

        In case of inhalation, consult a doctor immediately. Take the data sheet or label.

        4.2. Most important symptoms and effects, both acute and delayed.

        None

        4.3. Indication of any immediate medical attention and special treatment needed.

        In case of accident or experiencing symptoms, seek medical advice immediately (show

        directions for use or safety data sheet if possible).

        Treatment:

        None

         

        SECTION 5: Firefighting measures

        5.1. Extinguishing media

        Suitable extinguishing media:

        Foam Dry Chemical.

        Carbon dioxide (CO2).

        Extinguishing media which must not be used for safety reasons:

        High volume water jet.

        5.2. Special hazards arising from the substance or mixture

        May be released in case of fire: carbon monoxide, carbon dioxide, organic products of

        decomposition.

        Do not inhale explosion and combustion gases.

         

        Safety Data Sheet

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        Burning produces heavy smoke.

        5.3. Advice for firefighters

        Use suitable breathing apparatus.

        Keep away from heat/sparks/open flames/hot surfaces. No smoking. Take action to prevent.

        static discharges. In the event of fire, cool the endangered containers with water. When

        heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in

        air.

         

        Collect contaminated fire extinguishing water separately. This must not be discharged into

        drains.

         

        Move undamaged containers from immediate hazard area if it can be done safely.

         

        SECTION 6: Accidental release measures

        6.1. Personal precautions, protective equipment and emergency procedures

        Assure sufficient ventilation. Wear protective gloves/protective clothing/eye protection/face

        protection. Keep away sources of ignition. Use breathing apparatus if exposed to

        vapours/dust/mist/aerosol. Do not breathe vapours or spray mist. Do not eat, drink or smoke

        when using this product. Wash hands thoroughly with soap and water after handling.

        For non-emergency personnel:

        Wear personal protection equipment.

        Wear breathing apparatus if exposed to vapours/dusts/aerosols.

        Provide adequate ventilation.

        Use appropriate respiratory protection.

        See protective measures under point 7 and 8.

        For emergency responders:

        Wear personal protection equipment.

        6.2. Environmental precautions

        Do not allow to enter soil/subsoil. Do not allow to enter surface water or drains.

        Retain contaminated washing water and dispose of it.

        In case of escape or of entry into waterways, soil or drains, inform the responsible authorities.

        Suitable material for taking up: sand, earth, vermiculite etc.

        6.3. Methods and material for containment and cleaning up

        Wash with plenty of water.

        Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment!

        Smaller quantities and/or residues: Contain with absorbent material (e.g. sand, diatomaceous

        earth, acid absorbent, universal absorbent or sawdust). Dispose of in accordance with

        regulations.

        6.4. Reference to other sections

        See also section 8 and 13

        SECTION 7: Handling and storage

        7.1. Precautions for safe handling

        Do not breathe vapours. Absolutely avoid contact with the eyes and/or skin. Safety shower

        and eye wash fountain should be available.

        Do not eat, drink, or smoke during use.

        Keep away from heat/sparks/open flames/hot surfaces.

        No smoking.

        Take action to prevent static discharges. In the event of fire, cool the endangered containers.

         

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        with water.

        When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may

        form in air.

        Keep container tightly closed.

        Provide good room ventilation even at ground level (vapours are heavier than air).

        Methacrylic acid freezes at 15°C (59°F). Improper thawing can result in violent

        polymerization. The thawing of frozen drums can best be accomplished by placing them in a

        heated room at temperatures up to 40°C (104°F). This will allow the acid to melt slowly within

        a 48-hour period.

        DO NOT remove any material if stock is frozen or partially frozen. Mix during and after

        thawing to properly distribute inhibitor. NEVER use steam or electric heating bands.

         

        Use localized ventilation system.

        Ensure empty containers have been cleaned of any residue before reuse.

        Before transferring product, ensure that there are no traces of incompatible material residues

        in the containers.

        See also section 8 for recommended protective equipment.

        Advice on general occupational hygiene:

        Contaminated clothing should be changed before entering eating areas.

        Do not eat or drink while working.

        7.2. Conditions for safe storage, including any incompatibilities.

        Always keep in a well-ventilated place.

        Keep away from food, drink and feed.

        Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With

        large storage containers make sure the oxygen (air) supply is sufficient to ensure

        stability. Maintain the temperature of the methacrylic acid between 18°C and approx.

        35°C.Protect from light. The ideal storage temperature is 20-25°C.Can polymerize with intense.

        heat release. Higher temperature such as 40° C can be safely tolerated for short times such

        as during transportation or inventory turnover.

         

        Incompatible materials:

        None in particular.

        7.3. Specific end use(s)

        See section 1.2

        None in particular

         

        SECTION 8: Exposure controls/personal protection

        8.1. Control parameters

        methacrylic acid; 2-methylpropenoic acid - CAS: 79-41-4

        - OEL Type: EH40/2005 - TWA(8h): 72 mg/m3, 20 ppm - STEL: 143 mg/m3, 40 ppm

        - OEL Type: ACGIH - TWA(8h): 20 ppm - Notes: Skin and eye irr

        ethyl acetate - CAS: 141-78-6

        - OEL Type: EH40/2005 - TWA(8h): 200 ppm - STEL(15min): 400 ppm

        - OEL Type: EU - TWA(8h): 734 mg/m3, 200 ppm - STEL: 1468 mg/m3, 400 ppm

        - OEL Type: ACGIH - TWA(8h): 400 ppm - Notes: URT and eye irr

        butanone; ethyl methyl ketone - CAS: 78-93-3

        - OEL Type: EU - TWA(8h): 600 mg/m3, 200 ppm - STEL: 900 mg/m3, 300 ppm

        - OEL Type: ACGIH - TWA(8h): 200 ppm - STEL: 300 ppm - Notes: BEI - URT irr,

        CNS and PNS impair.

        DNEL Exposure Limit Values

         

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        methacrylic acid; 2-methylpropenoic acid - CAS: 79-41-4

        Worker Industry: 88 mg/m3 Exposure: Human Inhalation - Frequency: Long Term,

        systemic effects

        Worker Industry: 4.25 mg/kg - Exposure: Human Dermal - Frequency: Long Term,

        systemic effects - Endpoint: bw/day

        ethyl acetate - CAS: 141-78-6

        Worker Industry: 734 mg/m3 - Consumer: 367 mg/m3 - Exposure: Human Inhalation -

        Frequency: Long Term, systemic effects

        Worker Industry: 63 mg/kg - Consumer: 37 mg/kg - Exposure: Human Dermal -

        Frequency: Long Term, systemic effects - Endpoint: bw/day

        Consumer: 4.5 mg/kg - Exposure: Human Oral - Frequency: Long Term, systemic

        effects - Endpoint: bw/day

        PNEC Exposure Limit Values

        methacrylic acid; 2-methylpropenoic acid - CAS: 79-41-4

        Target: Fresh Water - Value: 0.82 mg/l

        Target: Marine water - Value: 0.82 mg/l

        Target: Soil (agricultural) - Value: 1.2 mg/kg

        ethyl acetate - CAS: 141-78-6

        Target: Fresh Water - Value: 0.24 mg/l

        Target: Marine water - Value: 0.024 mg/l

        Target: Intermittent releases - Value: 1.65 mg/l

        Target: Freshwater sediments - Value: 1.15 mg/kg

        Target: Soil (agricultural) - Value: 0.148 mg/kg

         

        8.2. Exposure controls

        Eye protection:

        Use close fitting safety goggles.

        Protection for skin:

        Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or

        viton. On handling of larger quantities: face mask, chemical-resistant boots and apron.

        Protection for hands:

        Material: Butyl rubber.

        Break-through time: 480 min

        Glove thickness: 0.3 mm

        Guideline: EN 374

        Additional Information: Please observe the instructions regarding permeability and

        breakthrough time which are provided by the supplier of the gloves. Also take into

        consideration the specific local conditions under which the product is used, such as the

        danger of cuts, abrasion, and the contact time., The above-mentioned hand protection is

        based on special knowledge of the chemical and the intended handling of this product,

        however, it still may not be suited for all workplaces. A qualified hazard assessment should be

        made prior to the onset of work in order to determine the suitability of gloves for specific

        working environments and processes. Gloves should be discarded and replaced if there is

        any indication of degradation or chemical breakthrough.

        Respiratory protection:

        Use respiratory protection where ventilation is insufficient, or exposure is prolonged.

        Use adequate protective respiratory equipment.

        Thermal Hazards:

        None

         

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        Environmental exposure controls:

        None

        Appropriate engineering controls:

        None

         

        SECTION 9: Physical and chemical properties

        9.1. Information on basic physical and chemical properties

        Properties Value Method: Notes

        Physical state: Liquid -- --

        Colour: Transparent -- --

        Odour: Characteristic -- --

        Melting point/freezing

        point:

         

        15.5°C -- --

         

        Boiling point or initial

        boiling point and boiling

        range:

         

        162°C -- --

         

        Flammability (solid, gas):: No data

        available

         

        -- --

         

        Flammability Limit - Upper

        (%):

         

        8.7 %(V)

        Flammability Limit - Lower

        (%):

         

        1.6 %(V)

         

        Vapor pressure: 0.97 hPa (20 °C)

        Vapor density (air=1): > 1 -- (20 °C)

        Flash point: 67°C -- --

        Auto-ignition temperature: 400°C -- --

        Decomposition

        temperature:

         

        N.A. -- --

        pH: 2.1 -- --

        Kinematic viscosity: N.A. -- --

        Dinamic viscosity: 1.38 mPa.s

        Solubility in water: 98 g/l -- (20 °C)

        Solubility (other): miscible with

        esters and

        ketones

        miscible with

        alcohols

         

        -- --

         

        Partition coefficient

        n-octanol/water (log value):

         

        0.93 -- --

        Vapour pressure: 0.97 hPa -- (20 °C)

        Density: 1.01 g/cm3 -- (20 °C)

         

        Particle characteristics:

        Particle size: N.A. -- --

        9.2. Other information

        No other relevant information

         

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        SECTION 10: Stability and reactivity

        10.1. Reactivity

        Stable under normal conditions

        10.2. Chemical stability

        Stable under normal conditions

        10.3. Possibility of hazardous reactions

        Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions. Product reacts

        violently to explosively with alkali metals, alkaline earth metals, various metal powders, strong

        alkalis and ammonia. Reactions with alkalis. Reacts vigorously with water producing

        heat. Contact with metals and water liberates hydrogen. Reactions with organic substances

        10.4. Conditions to avoid

        Stable under normal conditions. The product is normally supplied in a stabilized form. If the

        permissible storage period and/or storage temperature is exceeded, the product may

        polymerize with heat evolution.

        10.5. Incompatible materials

        Reactions with strong oxidizing agents 10.6. Hazardous decomposition products

        None when used as directed.

        SECTION 11: Toxicological information

        11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

        Toxicological information of the product:

        Methacrylic Acid Primer

        1. a) acute toxicity

        Not classified

        Based on available data, the classification criteria are not met

        1. b) skin corrosion/irritation

        The product is classified: Skin Corr. 1A H314

        1. c) serious eye damage/irritation

        The product is classified: Eye Dam. 1 H318

        1. d) respiratory or skin sensitisation

        Not classified

        Based on available data, the classification criteria are not met

        1. e) germ cell mutagenicity

        Not classified

        Based on available data, the classification criteria are not met

        1. f) carcinogenicity

        Not classified

        Based on available data, the classification criteria are not met

        1. g) reproductive toxicity

        Not classified

        Based on available data, the classification criteria are not met

        1. h) STOT-single exposure

        The product is classified: STOT SE 3 H335;STOT SE 3 H336

        1. i) STOT-repeated exposure

        Not classified

        Based on available data, the classification criteria are not met

        1. j) aspiration hazard

        Not classified

        Based on available data, the classification criteria are not met

         

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        Toxicological information of the main substances found in the product:

        methacrylic acid; 2-methylpropenoic acid - CAS: 79-41-4

        1. a) acute toxicity:

        Test: LD50 - Route: Oral - Species: Rat 1320 mg/kg bw

        Test: LC50 - Route: Inhalation - Species: Rat 7100 mg/m3

        Test: LD50 - Route: Skin - Species: Rabbit 500 mg/kg bw

        ethyl acetate - CAS: 141-78-6

        1. a) acute toxicity:

        Test: LD50 - Route: Oral - Species: Rabbit 4934 mg/kg

        Test: LD50 - Route: Skin - Species: Rabbit > 20000 mg/kg

        Test: LC50 - Route: Inhalation - Species: Rat > 22.5 mg/l

         

        11.2. Information on other hazards

        Endocrine disrupting properties:

        No endocrine disruptor substances present in concentration >= 0.1%

         

        SECTION 12: Ecological information

        12.1. Toxicity

        Adopt good working practices to avoid releasing the product into the environment.

        Methacrylic Acid Primer

        Not classified for environmental hazards

        Based on available data, the classification criteria are not met

        methacrylic acid; 2-methylpropenoic acid - CAS: 79-41-4

        1. a) Aquatic acute toxicity:

        Endpoint: N.A. - Species: Oncorhynchus mykiss (rainbow trout) 85 mg/l

        Endpoint: N.A. - Species: Daphnia > 130 mg/l

        Endpoint: N.A. - Species: Poecilia reticulata (guppy) 45 mg/l

         

        ethyl acetate - CAS: 141-78-6

        1. a) Aquatic acute toxicity:

        Endpoint: LC50 - Species: Fish 230 mg/l - Duration h: 96

        Endpoint: EC50 - Species: Daphnia 165 mg/l - Duration h: 48

        Endpoint: LC50 - Species: Algae 5600 mg/l - Duration h: 48

         

        12.2. Persistence and degradability

        methacrylic acid; 2-methylpropenoic acid - CAS: 79-41-4

        Biodegradability: Readily biodegradable

        ethyl acetate - CAS: 141-78-6

        Biodegradability: Readily biodegradable - %: 69

         

        12.3. Bioaccumulative potential

        methacrylic acid; 2-methylpropenoic acid - CAS: 79-41-4

        Low potential for bioaccumulation.

        ethyl acetate - CAS: 141-78-6

        Not bioaccumulative - Test: Kow - Partition coefficient -3

         

        12.4. Mobility in soil

        methacrylic acid; 2-methylpropenoic acid - CAS: 79-41-4

        Highly mobile in soils.

        12.5. Results of PBT and vPvB assessment

        vPvB Substances: None - PBT Substances: None

        12.6. Endocrine disrupting properties

        No endocrine disruptor substances present in concentration >= 0.1%

        12.7. Other adverse effects

        None

         

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        SECTION 13: Disposal considerations

        13.1. Waste treatment methods

        Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force.

         

        SECTION 14: Transport information

         

        14.1. UN number or ID number

        ADR-UN Number: 2531

        IATA-UN Number: 2531

        IMDG-UN Number: 2531

        14.2. UN proper shipping name

        ADR-Shipping Name: METHACRYLIC ACID, STABILIZED

        IATA-Shipping Name: METHACRYLIC ACID, STABILIZED

        IMDG-Shipping Name: METHACRYLIC ACID, STABILIZED

        14.3. Transport hazard class(es)

        ADR-Class: 8

        ADR - Hazard identification number: 89

        IATA-Class: 8

        IATA-Label: 8

        IMDG-Class: 8

        14.4. Packing group

        ADR-Packing Group: II

        IATA-Packing group: II

        IMDG-Packing group: II

        14.5. Environmental hazards

        ADR-Enviromental Pollutant: No

        IMDG-Marine pollutant: No

        IMDG-EmS: F-A , S-B

        14.6. Special precautions for user

        ADR-Subsidiary hazards: -

        ADR-S.P.: 386

        ADR-Transport category (Tunnel restriction code): 2 (E)

        IATA-Passenger Aircraft: 851

        IATA-Subsidiary hazards: -

        IATA-Cargo Aircraft: 855

        IATA-S.P.: A209

        IATA-ERG: 8L

        IMDG-Subsidiary hazards: -

        IMDG-Stowage and handling: Category C SW1 SW2

        IMDG-Segregation: SGG1 SG36 SG49

        14.7. Maritime transport in bulk according to IMO instruments

        N.A.

         

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        SECTION 15: Regulatory information

        15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

        Dir. 98/24/EC (Risks related to chemical agents at work)

        Dir. 2000/39/EC (Occupational exposure limit values)

        Regulation (EC) n. 1907/2006 (REACH)

        Regulation (EC) n. 1272/2008 (CLP)

        Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013

        Regulation (EU) n. 2020/878

        Regulation (EU) n. 286/2011 (ATP 2 CLP)

        Regulation (EU) n. 618/2012 (ATP 3 CLP)

        Regulation (EU) n. 487/2013 (ATP 4 CLP)

        Regulation (EU) n. 944/2013 (ATP 5 CLP)

        Regulation (EU) n. 605/2014 (ATP 6 CLP)

        Regulation (EU) n. 2015/1221 (ATP 7 CLP)

        Regulation (EU) n. 2016/918 (ATP 8 CLP)

        Regulation (EU) n. 2016/1179 (ATP 9 CLP)

        Regulation (EU) n. 2017/776 (ATP 10 CLP)

        Regulation (EU) n. 2018/669 (ATP 11 CLP)

        Regulation (EU) n. 2018/1480 (ATP 13 CLP)

        Regulation (EU) n. 2019/521 (ATP 12 CLP)

        Regulation (EU) n. 2020/217 (ATP 14 CLP)

        Regulation (EU) n. 2020/1182 (ATP 15 CLP)

        Regulation (EU) n. 2021/643 (ATP 16 CLP)

        Restrictions related to the product, or the substances contained according to Annex XVII Regulation

        (EC) 1907/2006 (REACH) and subsequent modifications:

        Restrictions related to the product:

        Restriction 3

        Restriction 40

        Restrictions related to the substances contained:

        Restriction 75

         

        Where applicable, refer to the following regulatory provisions :

        Directive 2012/18/EU (Seveso III)

        Regulation (EC) nr 648/2004 (detergents).

        Dir. 2004/42/EC (VOC directive)

        Provisions related to directive EU 2012/18 (Seveso III):

        Seveso III category according to Annex 1, part 1

        None

         

        15.2. Chemical safety assessment

        A Chemical Safety Assessment has not been carried out for the mixture.

         

        SECTION 16: Other information

        Full text of phrases referred to in Section 3:

        H314 Causes severe skin burns and eye damage.

        H302 Harmful if swallowed.

        H312 Harmful in contact with skin.

        H335 May cause respiratory irritation.

        H225 Highly flammable liquid and vapour.

         

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        H319 Causes serious eye irritation.

        H336 May cause drowsiness or dizziness.

        EUH066 Repeated exposure may cause skin dryness or cracking.

        Hazard class and

        hazard category

         

        Code Description

         

        Flam. Liq. 2 2.6/2 Flammable liquid, Category 2

        Acute Tox. 4 3.1/4/Dermal Acute toxicity (dermal), Category 4

        Acute Tox. 4 3.1/4/Oral Acute toxicity (oral), Category 4

        Skin Corr. 1A 3.2/1A Skin corrosion, Category 1A

        Eye Dam. 1 3.3/1 Serious eye damage, Category 1

        Eye Irrit. 2 3.3/2 Eye irritation, Category 2

        STOT SE 3 3.8/3 Specific target organ toxicity - single exposure,

         

        Category 3

         

        Classification and procedure used to derive the classification for mixtures according to Regulation

        (EC) 1272/2008 [CLP]:

        Classification according to Regulation (EC) Nr.

        1272/2008

         

        Classification procedure

        Skin Corr. 1A, H314 Calculation method

        Eye Dam. 1, H318 Calculation method

        STOT SE 3, H335 Calculation method

        STOT SE 3, H336 Calculation method

        This document was prepared by a competent person who has received appropriate training.

        Main bibliographic sources:

        ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,

        Commission of the European Communities

        SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van

        Nostrand Reinold

        The information contained herein is based on our state of knowledge at the above-specified date. It

        refers solely to the product indicated and constitutes no guarantee of particular quality.

        It is the duty of the user to ensure that this information is appropriate and complete with respect to

        the specific use intended.

        This MSDS cancels and replaces any preceding release.

        ADR: European Agreement concerning the International Carriage of

         

        Dangerous Goods by Road.

        ATE: Acute Toxicity Estimate

        ATEmix: Acute toxicity Estimate (Mixtures)

        CAS: Chemical Abstracts Service (division of the American Chemical

         

        Society).

         

        CLP: Classification, Labelling, Packaging.

        DNEL: Derived No Effect Level.

        EINECS: European Inventory of Existing Commercial Chemical Substances.

        GefStoffVO: Ordinance on Hazardous Substances, Germany.

        GHS: Globally Harmonized System of Classification and Labelling of Chemicals.

         

        IATA: International Air Transport Association.

         

        Safety Data Sheet

        Methacrylic Acid Primer

         

        I132 0000/2

        Page n. 13 of 13

        IATA-DGR: Dangerous Goods Regulation by the "International Air Transport

         

        Association" (IATA).

         

        ICAO: International Civil Aviation Organization.

        ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"

         

        (ICAO).

         

        IMDG: International Maritime Code for Dangerous Goods.

        INCI: International Nomenclature of Cosmetic Ingredients.

        KSt: Explosion coefficient.

        LC50: Lethal concentration, for 50 percent of test population.

        LD50: Lethal dose, for 50 percent of test population.

        PNEC: Predicted No Effect Concentration.

        RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.

         

        STEL: Short Term Exposure limit.

        STOT: Specific Target Organ Toxicity.

        TLV: Threshold Limiting Value.

        TWA: Time-weighted average

        WGK: German Water Hazard Class

         

        Disclaimer

        Claw Culture Cosmetics Limited works tirelessly to work with established manufacturers.  It is the purchaser’s responsibility to ensure that the product is suitable for their requirements and undertake a personal Risk Assessment prior to use.  All information appearing herein is obtained from the manufacturers. While the information is believed to be accurate to the best of our knowledge and belief Claw Culture Cosmetics Limited makes no representation as to its accuracy or sufficiency. Judgement as to the suitability of products are the purchaser’s sole responsibility.