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        Claw Culture Cosmetics Limited

        Contact Information: Claw Culture Cosmetics Limited, c/o Unit 6 Park Road Industrial Estate, BACUP, Lancashire, OL13 0BW.  sales@clawculture.com

        Website: www.clawculture.com

        Emergency Contact Number: 07495 930061

        Product Name : Claw Culture Acrylic Powder

        1. HAZARDS IDENTIFICATION

        GHS CLASSIFICATIONS

        Combustible Dust

        Skin Sensitization (Category 1), H317

        Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 100%

        GHS LABEL

         

        SIGNAL WORD: WARNING

        Hazard statement(s)

        May form combustible dust concentrations in air

        H317 May cause an allergic skin reaction

        Precautionary statement(s)

        P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

        P280 Wear protective gloves/ eye protection/ face protection.

        Prevention:

        1. COMPOSITION / INFORMATION ON INGREDIENTS

        There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as

        hazardous to health or the environment and hence require reporting in this section. May contain one or more of the following components

        in quantities considered hazardous:

        Chemical Name Vol. % CAS

        Polyethyl methacrylate 50-75 9003-42-3

        Polymethyl methacrylate 25-50 9011-14-7

        D&C yellow #10 0-10 8004-92-0

        Dibenzoyl Peroxide 0-5 94-36-0

        Silicon dioxide(Silica) 0-0.1 112945-52-2

        1. FIRST AID MEASURES

        4.1 Description of first aid measures

        General advice

        Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area.

        If inhaled, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

        In case of skin contact wash off with soap and plenty of water. Consult a physician.

        In case of eye contact rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Continue rinsing eyes during transport to hospital.

        If swallowed, never give anything by mouth to an unconscious person. Do NOT induce vomiting. Rinse mouth with water. Consult a physician.

        4.2 Most important symptoms and effects, both acute and delayed.

        The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

        4.3 Indication of any immediate medical attention and special treatment needed.

        no data available

        1. FIRE FIGHTING MEASURES

        5.1 Extinguishing media

        Suitable extinguishing media

        Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

        5.2 Special hazards arising from the substance or mixture

        Carbon oxides

        5.3 Advice for firefighters

        Wear self-contained breathing apparatus for firefighting if necessary.

        5.4 Further information

        Use water spray to cool unopened containers.

        1. ACCIDENTAL RELEASE MEASURES

        6.1 Personal precautions, protective equipment and emergency procedures

        Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.

        6.2 Environmental precautions

        Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

        6.3 Methods and materials for containment and cleaning up

        Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal

        according to local regulations (see section 13).

        1. HANDLING AND STORAGE

        7.1 Precautions for safe handling

        Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Use explosion-proof equipment. Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge.

        7.2 Conditions for safe storage, including any incompatibilities.

        Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept.

        upright to prevent leakage.

        7.3 Specific end use(s)

        Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

        1. EXPOSURE CONTROLS / PERSONAL PROTECTION

        Control parameters

        Exposure limits

        Component CAS-No. Value Control

        parameters

        Basis

        Benzoyl Peroxide 94-36-7 TWA 5 mg/m3 USA. ACGIH Threshold Limit Values

        (TLV)

        TWA 5 mg/m3 USA. Occupational Exposure Limits

        (OSHA) - Table Z-1 Limits for Air

         

        Contaminants

        Exposure controls

        Appropriate engineering controls

        Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker.

        exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-prof ventilation equipment.

        Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

        Personal protective equipment

        Eye/face protection

        Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

        Skin protection

        Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

        Body Protection

        Complete suit protecting against chemicals, the type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

        Personal protective equipment.

        Respiratory protection

        Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN14287) respirator cartridges as a backup to engineering controls if the respirator is the sole means of protection, use a

        full0face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH or CEN

        Control of environmental exposure

        Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

        1. PHYSICAL AND CHEMICAL PROPERTIES

        Appearance: Solid, Powder

        Odour: no data available

        Odour threshold: no data available

        pH: no data available

        Melting point/freezing point: no data available

        Solubility: no data available

        Initial boiling point and boiling range: no data available

        Flash point: >93.3o

         

        C (closed cup)

        Evaporation rate: no data available

        Flammability: no data available

        Upper/lower flammability or explosive limits: no data available

        Vapor pressure: no data available

        Vapor density: no data available

        Relative density: no data available

        Partition coefficient: n-octanol/water:

        Auto-ignition temperature: no data available

        Decomposition temperature: no data available

        Viscosity: no data available

        1. STABILITY AND REACTIVITY

        Reactivity

        No data available

        10.2 Chemical stability

        Stable under recommended storage conditions.

        10.3 Possibility of hazardous reactions

        Vapours may form explosive mixture with air.

        10.4 Conditions to avoid

        Heat, flames and sparks. Extremes of temperature and direct sunlight.

        10.5 Incompatible materials

        Oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides, halogenated compounds

        10.6 Hazardous decomposition products

        No data available

         

        In the event of fire: see section 5

        1. TOXICOLOGICAL INFORMATION

        Acute toxicity:

        Substance/Ingredient Test results Species

        D&C yellow #10 LD50 Oral – 2 g/kg Rat

        Dibenzoyl Peroxide LD50 Oral – 6,400 mg/kg Rat

        Substance/Ingredient Skin corrosion/irritation Eye damage/irritation Respiration

        sensitization

         

        Skin sensitization

        No data available No data available No data available No data available

        Severe irritant Mild irritant No data available No data available

         

        Description of the delayed, immediate, or chronic effects from short- and long-term exposure

        Specific target organ toxicity – single exposure

        Inhalation, oral - May cause drowsiness or dizziness.

        Specific target organ toxicity – repeated exposure

        No data available

        Chronic health effects

        Substance/Ingredient Germ Cell mutagenicity Carcinogenicity Reproductive toxicity

        D&C yellow #10 no data available No known significant effects no data available

        Dibenzoyl Peroxide no data available IARC – Group 3 no data available

        Aspiration hazard

        no data available

        Additional Information

        1. ECOLOGICAL INFORMATION

        Toxicity

        Substance/Ingredient Test Species Exposure

        D&C yellow #10 n/a

        Dibenzoyl Peroxide EC50 – 0.83 mg/l

        EC50 0.07 mg/l

        LC50 2 mg/l

         

        Algae

        Daphnia

        Fish

        72 h

        48 h

        96 h

        Persistence and degradability

        Substance/Ingredient Persistence/degradable

        Poly (ethyl methacrylate) n/a

        Poly (methyl methacrylate) n/a

        Dibenzoyl Peroxide n/a

        Bio accumulative potential

        n/a

        Mobility in soil

        n/a

        PBT and vPVB assessment

        n/a

        Other adverse effects

        n/a

        1. DISPOSAL CONSIDERATIONS

        DISPOSAL METHOD: Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material.

        is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

         

        1. TRANSPORT INFORMATION

        DOT (DEPARTMENT OF TRANSPORTATION)

        PROPER SHIPPING NAME:

        PRIMARY HAZARD CLASS/DIVISION:

        UN/NA NUMBER:

        PACKING GROUP:

        REPORTABLE QUANTITY (RQ) UNDER CERCLA:

        LABEL:

        1. REGULATORY INFORMATION

        SARA 302 Components

        SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

        SARA 313 Components

        2-Propanol

        SARA 311/312 Hazards

        Fire Hazard, Acute Health Hazard

        Massachusetts Right To Know Components

        DIETHYL PHTHALATE; Mica; TITANIUM

        DIOXIDE; BENZOYL PEROXIDE; FD & C blue #1; Red iron oxide

        Pennsylvania Right To Know Components

        1,2-BENZENEDICARBOXYLIC ACID, DIETHYL

        ESTER; TITANIUM OXIDE (TIO2); PEROXIDE, DIBENZOYL; Manganese violet; Red

        iron oxide

        New Jersey Right To Know Components

        DIETHYL PHTHALATE; 1,

        2-BENZENEDICARBOXYLIC ACID, DIETHYL ESTER; DEP; Mica; TITANIUM

        DIOXIDE; TITANIUM OXIDE (TiO2); BENZOYL PEROXIDE; DIBENZOYLPEROXIDE;

        Red iron oxide

        California Prop. 65 Components

        Titanium Dioxide

        1. OTHER INFORMATION

        MANUFACTURER DISCLAIMER: The information presented herein is believed to be accurate. Recipients are advised to confirm in advance that the information is current, applicable and suitable to their circumstances. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages.

        HMIS Rating

        Health hazard: 1

        Chronic Health Hazard:

        Flammability: 1

        Physical Hazard 1

        NFPA Rating

        Health hazard: 1

        Fire Hazard: 1

        Reactivity Hazard: 1

        Disclaimer

        Claw Culture Cosmetics Limited works tirelessly to work with established manufacturers.  It is the purchaser’s responsibility to ensure that the product is suitable for their requirements and undertake a personal Risk Assessment prior to use.  All information appearing herein is obtained from the manufacturers. While the information is believed to be accurate to the best of our knowledge and belief Claw Culture Cosmetics Limited makes no representation as to its accuracy or sufficiency. Judgement as to the suitability of products are the purchaser’s sole responsibility.