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        Claw Culture Cosmetics Limited

        Contact Information Claw Culture Cosmetics Limited, c/o Unit 6 Park Road Industrial Estate, BACUP, Lancashire, OL13 0BW.  sales@clawculture.com

        Website: www.clawculture.com

        Emergency Contact Number 07495 930061

        Product Name: Premium Cosmetic Monomer Violet

        SECTION 2: Hazards identification

        2.1. Classification of the substance or mixture

        EC regulation criteria 1272/2008 (CLP)

        Danger, Flam. Liq. 2, Highly flammable liquid and vapour.

        Warning, Skin Irrit. 2, Causes skin irritation.

        Warning, Eye Irrit. 2, Causes serious eye irritation.

        Warning, Skin Sens. 1B, May cause an allergic skin reaction.

        Warning, STOT SE 3, May cause respiratory irritation.

        Adverse physicochemical, human health and environmental effects:

        No other hazards

        2.2. Label elements

        Hazard pictograms:

        Safety Data Sheet

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        Danger

        Hazard statements:

        H225 Highly flammable liquid and vapour.

        H315 Causes skin irritation.

        H319 Causes serious eye irritation.

        H317 May cause an allergic skin reaction.

        H335 May cause respiratory irritation.

        Precautionary statements:

        P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

        smoking.

        P240 Ground and bond container and receiving equipment.

        P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

        P271 Use only outdoors or in a well-ventilated area.

        P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing

        protection

        P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.

        Rinse skin with water [or shower].

        P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

        P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

        contact lenses, if present and easy to do. Continue rinsing.

        P312 Call a POISON CENTER/doctor if you feel unwell.

        P405 Store locked up.

        P501 Dispose of contents/container in accordance with applicable regulations.

        Special Provisions:

        None

        Contains

        ethyl methacrylate

        tetraethylene glycol dimethacrylate

        Hydroxypropyl Methacrylate: May produce an allergic reaction.

        Special provisions according to Annex XVII of REACH and subsequent amendments:

        None

        2.3. Other hazards

        No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%

        Other Hazards:

        No other hazards

         

        SECTION 3: Composition/information on ingredients

        3.1. Substances

        N.A.

        3.2. Mixtures

        Hazardous components within the meaning of the CLP regulation and related classification or

        which have been assigned Occupational Exposure Limits:

        Qty Name Ident. Number Classification

         

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        < 90% ethyl methacrylate Index

        number:

         

        607-071-00-2

        CAS: 97-63-2

        EC: 202-597-5

         

        2.6/2 Flam. Liq. 2 H225

        3.3/2 Eye Irrit. 2 H319

        3.8/3 STOT SE 3 H335

        3.2/2 Skin Irrit. 2 H315

        3.4.2/1 Skin Sens. 1 H317

         

        < 10% Hydroxypropyl

        Methacrylate

         

        CAS: 27813-02-1

        EC: 248-666-3

        REACH No.: 01-21194902

        26-37

         

        3.3/2 Eye Irrit. 2 H319

        3.4.2/1 Skin Sens. 1 H317

         

        < 7% tetraethylene glycol

        dimethacrylate

         

        CAS: 109-17-1

        EC: 203-653-1 3.4.2/1B Skin Sens. 1B H317

         

        SECTION 4: First aid measures

        4.1. Description of first aid measures

        In case of skin contact:

        Remove contaminated clothing immediately and dispose of safely.

        After contact with skin, wash immediately with soap and water.

        In case of eye contact:

        After contact with the eyes, rinse with water with the eyelids open for 15 minutes, then seek

        prompt medical advice.

        Protect uninjured eye.

        In case of ingestion:

        Do not induce vomiting. Immediately rinse mouth and drink plenty of water. Keep person

        under observation. If person becomes uncomfortable remove to hospital and bring these

        instructions.

        In case of inhalation:

        In case of inhalation, consult a doctor immediately. Take the data sheet or label.

        4.2. Most important symptoms and effects, both acute and delayed

        None

        4.3. Indication of any immediate medical attention and special treatment needed

        In case of accident or experiencing symptoms, seek medical advice immediately (show

        directions for use or safety data sheet if possible).

        Treatment:

        None

         

        SECTION 5: Firefighting measures

        5.1. Extinguishing media

        Suitable extinguishing media:

        Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder. Use water

        spray to cool containers

        Extinguishing media which must not be used for safety reasons:

        None in particular.

        5.2. Special hazards arising from the substance or mixture

        Do not inhale explosion and combustion gases.

        Burning produces heavy smoke.

        5.3. Advice for firefighters

        Use suitable breathing apparatus .

         

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        Collect contaminated fire extinguishing water separately. This must not be discharged into

        drains.

        Move undamaged containers from immediate hazard area if it can be done safely.

         

        SECTION 6: Accidental release measures

        6.1. Personal precautions, protective equipment and emergency procedures

        For non emergency personnel:

        Wear personal protection equipment.

        Remove all sources of ignition.

        Wear breathing apparatus if exposed to vapours/dusts/aerosols.

        Provide adequate ventilation.

        Use appropriate respiratory protection.

        See protective measures under point 7 and 8.

        For emergency responders:

        Wear personal protection equipment.

        6.2. Environmental precautions

        Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.

        Retain contaminated washing water and dispose of it.

        In case of escape or of entry into waterways, soil or drains, inform the responsible authorities.

        Suitable material for taking up: sand, earth, vermiculite etc.

        6.3. Methods and material for containment and cleaning up

        Wash with plenty of water.

        6.4. Reference to other sections

        See also section 8 and 13

        SECTION 7: Handling and storage

        7.1. Precautions for safe handling

        Avoid contact with skin and eyes, inhalation of vapours and mists.

        Use localized ventilation system.

        Ensure empty containers have been cleaned of any residue before reuse.

        Before transferring product, ensure that there are no traces of incompatible material residues

        in the containers.

        See also section 8 for recommended protective equipment.

        Advice on general occupational hygiene:

        Contaminated clothing should be changed before entering eating areas.

        Do not eat or drink while working.

        7.2. Conditions for safe storage, including any incompatibilities

        Always keep in a well ventilated place.

        Store at below 20 °C. Keep away from unguarded flame and heat sources. Avoid direct

        exposure to sunlight.

        Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to

        sunlight.

        Avoid accumulating electrostatic charge.

        Keep away from food, drink and feed.

        Incompatible materials:

        None in particular.

        Instructions as regards storage premises:

        Cool and adequately ventilated.

        Safety electric system.

        7.3. Specific end use(s)

         

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        See section 1.2

        None in particular

         

        SECTION 8: Exposure controls/personal protection

        8.1. Control parameters

        No data available

        DNEL Exposure Limit Values

        N.A.

        PNEC Exposure Limit Values

        N.A.

        8.2. Exposure controls

        Eye protection:

        Use close fitting safety goggles.

        Protection for skin:

        Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or

        viton.

        Protection for hands:

        Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or

        rubber.

        Respiratory protection:

        Use respiratory protection where ventilation is insufficient or exposure is prolonged.

        Thermal Hazards:

        None

        Environmental exposure controls:

        None

        Appropriate engineering controls:

        None

         

        SECTION 9: Physical and chemical properties

        9.1. Information on basic physical and chemical properties

        Properties Value Method: Notes

        Physical state: Liquid -- --

        Colour: Violet -- --

        Odour: Characteristic -- --

        Melting point/freezing

        point:

         

        N.A. -- --

         

        Boiling point or initial

        boiling point and boiling

        range:

         

        N.A. -- --

         

        Flammability: Flam. Liq. 2,

        H225

         

        -- --

         

        Lower and upper explosion

        limit:

         

        N.A. -- --

        Flash point: 21°C -- --

        Auto-ignition temperature: N.A. -- --

        Decomposition

        temperature:

         

        N.A. -- --

        pH: 6 -- --

        Kinematic viscosity: N.A. -- --

         

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        Solubility in water: N.A. -- --

        Solubility in oil: N.A. -- --

        Partition coefficient

        n-octanol/water (log value):

         

        N.A. -- --

        Vapour pressure: N.A. -- --

        Density and/or relative

        density:

         

        0.94 -- --

        Relative vapour density: N.A. -- --

        Particle characteristics:

        Particle size: N.A. -- --

        9.2. Other information

        No other relevant information

        SECTION 10: Stability and reactivity

        10.1. Reactivity

        Stable under recommended transport or storage conditions.

        10.2. Chemical stability

        Stable under normal conditions.

        10.3. Possibility of hazardous reactions

        Hazardous reactions will not occur under normal transport or storage conditions.

        Decomposition may occur on exposure to conditions or materials listed below.

        10.4. Conditions to avoid

        Heat. Direct sunlight. Sources of ignition. Flames.

        10.5. Incompatible materials

        Strong oxidising agents. Strong acids.The product could catch fire.

        10.6. Hazardous decomposition products

        In combustion emits toxic fumes.

        SECTION 11: Toxicological information

        11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

        Toxicological information of the product:

        Premium Cosmetic Monomer Violet

        1. a) acute toxicity

        Not classified

        Based on available data, the classification criteria are not met

        1. b) skin corrosion/irritation

        The product is classified: Skin Irrit. 2 H315

        1. c) serious eye damage/irritation

        The product is classified: Eye Irrit. 2 H319

        1. d) respiratory or skin sensitisation

        The product is classified: Skin Sens. 1B H317

        1. e) germ cell mutagenicity

        Not classified

        Based on available data, the classification criteria are not met

        1. f) carcinogenicity

        Not classified

        Based on available data, the classification criteria are not met

        1. g) reproductive toxicity

         

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        Not classified

        Based on available data, the classification criteria are not met

        1. h) STOT-single exposure

        The product is classified: STOT SE 3 H335

        1. i) STOT-repeated exposure

        Not classified

        Based on available data, the classification criteria are not met

        1. j) aspiration hazard

        Not classified

        Based on available data, the classification criteria are not met

        Toxicological information of the main substances found in the product:

        Hydroxypropyl Methacrylate - CAS: 27813-02-1

        1. a) acute toxicity:

        Test: LD50 - Route: Oral - Species: Rat > 5000 mg/kg

        Test: LD50 - Route: Skin - Species: Rabbit >= 5000 mg/kg

        tetraethylene glycol dimethacrylate - CAS: 109-17-1

        1. a) acute toxicity:

        Test: LD50 - Route: Oral - Species: Rat > 5000 mg/kg

        Test: LD50 - Route: Skin - Species: Rabbit > 3000 mg/kg

         

        11.2. Information on other hazards

        Endocrine disrupting properties:

        No endocrine disruptor substances present in concentration >= 0.1%

         

        SECTION 12: Ecological information

        12.1. Toxicity

        Adopt good working practices to avoid releasing the product into the environment.

        Premium Cosmetic Monomer Violet

        Not classified for environmental hazards

        Based on available data, the classification criteria are not met

        Hydroxypropyl Methacrylate - CAS: 27813-02-1

        1. a) Aquatic acute toxicity:

        Endpoint: LC50 - Species: Fish = 493 mg/l - Duration h: 48

        Endpoint: EC50 - Species: Daphnia > 143 mg/l - Duration h: 48

         

        tetraethylene glycol dimethacrylate - CAS: 109-17-1

        1. a) Aquatic acute toxicity:

        Endpoint: EC50 - Species: Daphnia 391 mg/l - Duration h: 48

        Endpoint: EC50 - Species: Algae 68 mg/l - Duration h: 72

         

        12.2. Persistence and degradability

        Hydroxypropyl Methacrylate - CAS: 27813-02-1

        Biodegradability: Readily biodegradable

        tetraethylene glycol dimethacrylate - CAS: 109-17-1

        Biodegradability: Readily biodegradable

         

        12.3. Bioaccumulative potential

        Hydroxypropyl Methacrylate - CAS: 27813-02-1

        Not bioaccumulative - Test: BCF - Bioconcentration factor 100

         

        12.4. Mobility in soil

        Hydroxypropyl Methacrylate - CAS: 27813-02-1

        No data available.

         

        12.5. Results of PBT and vPvB assessment

        vPvB Substances: None - PBT Substances: None

         

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        12.6. Endocrine disrupting properties

        No endocrine disruptor substances present in concentration >= 0.1%

        12.7. Other adverse effects

        None

         

        SECTION 13: Disposal considerations

        13.1. Waste treatment methods

        Recover, if possible. Send to authorised disposal plants or for incineration under controlled

        conditions. In so doing, comply with the local and national regulations currently in force.

         

        SECTION 14: Transport information

         

        14.1. UN number or ID number

        ADR-UN Number: 1993

        IATA-UN Number: 1993

        IMDG-UN Number: 1993

        14.2. UN proper shipping name

        ADR-Shipping Name: FLAMMABLE LIQUID, N.O.S. (ethyl methacrylate,

        1-methoxy-2-propanol; monopropylene glycol methyl ether)

        IATA-Shipping Name: FLAMMABLE LIQUID, N.O.S. (ethyl methacrylate,

        1-methoxy-2-propanol; monopropylene glycol methyl ether)

        IMDG-Shipping Name: FLAMMABLE LIQUID, N.O.S. (ethyl methacrylate,

        1-methoxy-2-propanol; monopropylene glycol methyl ether)

         

        14.3. Transport hazard class(es)

        ADR-Class: 3

        ADR - Hazard identification number: 33

        IATA-Class: 3

        IATA-Label: 3

        IMDG-Class: 3

        14.4. Packing group

        ADR-Packing Group: II

        IATA-Packing group: II

        IMDG-Packing group: II

        14.5. Environmental hazards

        ADR-Enviromental Pollutant: No

        IMDG-Marine pollutant: No

        IMDG-EmS: F-E , S-E

        14.6. Special precautions for user

        ADR-Subsidiary hazards: -

        ADR-S.P.: 274 601 640C

        ADR-Transport category (Tunnel restriction code): 2 (D/E)

        IATA-Passenger Aircraft: 353

        IATA-Subsidiary hazards: -

        IATA-Cargo Aircraft: 364

         

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        IATA-S.P.: A3

        IATA-ERG: 3H

        IMDG-Subsidiary hazards: -

        IMDG-Stowage and handling: Category B

        IMDG-Segregation: -

        14.7. Maritime transport in bulk according to IMO instruments

        N.A.

         

        SECTION 15: Regulatory information

        15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

        Dir. 98/24/EC (Risks related to chemical agents at work)

        Dir. 2000/39/EC (Occupational exposure limit values)

        Regulation (EC) n. 1907/2006 (REACH)

        Regulation (EC) n. 1272/2008 (CLP)

        Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013

        Regulation (EU) n. 2020/878

        Regulation (EU) n. 286/2011 (ATP 2 CLP)

        Regulation (EU) n. 618/2012 (ATP 3 CLP)

        Regulation (EU) n. 487/2013 (ATP 4 CLP)

        Regulation (EU) n. 944/2013 (ATP 5 CLP)

        Regulation (EU) n. 605/2014 (ATP 6 CLP)

        Regulation (EU) n. 2015/1221 (ATP 7 CLP)

        Regulation (EU) n. 2016/918 (ATP 8 CLP)

        Regulation (EU) n. 2016/1179 (ATP 9 CLP)

        Regulation (EU) n. 2017/776 (ATP 10 CLP)

        Regulation (EU) n. 2018/669 (ATP 11 CLP)

        Regulation (EU) n. 2018/1480 (ATP 13 CLP)

        Regulation (EU) n. 2019/521 (ATP 12 CLP)

        Regulation (EU) n. 2020/217 (ATP 14 CLP)

        Regulation (EU) n. 2020/1182 (ATP 15 CLP)

        Regulation (EU) n. 2021/643 (ATP 16 CLP)

        Restrictions related to the product or the substances contained according to Annex XVII Regulation

        (EC) 1907/2006 (REACH) and subsequent modifications:

        Restrictions related to the product:

        Restriction 3

        Restriction 40

        Restrictions related to the substances contained:

        Restriction 75

         

        Where applicable, refer to the following regulatory provisions :

        Directive 2012/18/EU (Seveso III)

        Regulation (EC) nr 648/2004 (detergents).

        Dir. 2004/42/EC (VOC directive)

        Provisions related to directive EU 2012/18 (Seveso III):

        Seveso III category according to Annex 1, part 1

        Product belongs to category: P5c

         

        15.2. Chemical safety assessment

        A Chemical Safety Assessment has not been carried out for the mixture.

         

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        SECTION 16: Other information

        Full text of phrases referred to in Section 3:

        H225 Highly flammable liquid and vapour.

        H319 Causes serious eye irritation.

        H335 May cause respiratory irritation.

        H315 Causes skin irritation.

        H317 May cause an allergic skin reaction.

        H373 May cause damage to organs through prolonged or repeated exposure.

        H412 Harmful to aquatic life with long lasting effects.

        H301 Toxic if swallowed.

        H311 Toxic in contact with skin.

        H331 Toxic if inhaled.

        H226 Flammable liquid and vapour.

        H336 May cause drowsiness or dizziness.

        Hazard class and

        hazard category

         

        Code Description

         

        Flam. Liq. 2 2.6/2 Flammable liquid, Category 2

        Flam. Liq. 3 2.6/3 Flammable liquid, Category 3

        Acute Tox. 3 3.1/3/Dermal Acute toxicity (dermal), Category 3

        Acute Tox. 3 3.1/3/Inhal Acute toxicity (inhalation), Category 3

        Acute Tox. 3 3.1/3/Oral Acute toxicity (oral), Category 3

        Skin Irrit. 2 3.2/2 Skin irritation, Category 2

        Eye Irrit. 2 3.3/2 Eye irritation, Category 2

        Skin Sens. 1 3.4.2/1 Skin Sensitisation, Category 1

        Skin Sens. 1B 3.4.2/1B Skin Sensitisation, Category 1B

        STOT SE 3 3.8/3 Specific target organ toxicity - single exposure,

         

        Category 3

         

        STOT RE 2 3.9/2 Specific target organ toxicity - repeated

         

        exposure, Category 2

         

        Aquatic Chronic 3 4.1/C3 Chronic (long term) aquatic hazard, category 3

        Classification and procedure used to derive the classification for mixtures according to Regulation

        (EC) 1272/2008 [CLP]:

        Classification according to Regulation (EC) Nr.

        1272/2008

         

        Classification procedure

        Flam. Liq. 2, H225 On basis of test data

        Skin Irrit. 2, H315 Calculation method

        Eye Irrit. 2, H319 Calculation method

        Skin Sens. 1B, H317 Calculation method

        STOT SE 3, H335 Calculation method

        This document was prepared by a competent person who has received appropriate training.

        Main bibliographic sources:

        ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,

        Commission of the European Communities

        SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van

        Nostrand Reinold

         

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        The information contained herein is based on our state of knowledge at the above-specified date. It

        refers solely to the product indicated and constitutes no guarantee of particular quality.

        It is the duty of the user to ensure that this information is appropriate and complete with respect to

        the specific use intended.

        This MSDS cancels and replaces any preceding release.

        ADR: European Agreement concerning the International Carriage of

         

        Dangerous Goods by Road.

        ATE: Acute Toxicity Estimate

        ATEmix: Acute toxicity Estimate (Mixtures)

        CAS: Chemical Abstracts Service (division of the American Chemical

         

        Society).

         

        CLP: Classification, Labeling, Packaging.

        DNEL: Derived No Effect Level.

        EINECS: European Inventory of Existing Commercial Chemical Substances.

        GefStoffVO: Ordinance on Hazardous Substances, Germany.

        GHS: Globally Harmonized System of Classification and Labeling of

         

        Chemicals.

         

        IATA: International Air Transport Association.

        IATA-DGR: Dangerous Goods Regulation by the "International Air Transport

         

        Association" (IATA).

         

        ICAO: International Civil Aviation Organization.

        ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"

         

        (ICAO).

         

        IMDG: International Maritime Code for Dangerous Goods.

        INCI: International Nomenclature of Cosmetic Ingredients.

        KSt: Explosion coefficient.

        LC50: Lethal concentration, for 50 percent of test population.

        LD50: Lethal dose, for 50 percent of test population.

        PNEC: Predicted No Effect Concentration.

        RID: Regulation Concerning the International Transport of Dangerous Goods

         

        by Rail.

         

        STEL: Short Term Exposure limit.

        STOT: Specific Target Organ Toxicity.

        TLV: Threshold Limiting Value.

        TWA: Time-weighted average

        WGK: German Water Hazard Class.

         

        Disclaimer

        Claw Culture Cosmetics Limited works tirelessly to work with established manufacturers.  It is the purchaser’s responsibility to ensure that the product is suitable for their requirements and undertake a personal Risk Assessment prior to use.  All information appearing herein is obtained from the manufacturers. While the information is believed to be accurate to the best of our knowledge and belief Claw Culture Cosmetics Limited makes no representation as to its accuracy or sufficiency. Judgement as to the suitability of products are the purchaser’s sole responsibility.